Improving the Performance Properties of Chromium-Molybdenum- Vanadium steel 30X3MF for Automotive Parts by Nitrocementation in an Active Medium
https://doi.org/10.21869/2223-1528-2022-12-1-41-53
Abstract
Purpose of research to study the effect of nitrocementation of chromium-molybdenum-vanadium steel 30X3MF in a highly active paste-like nitrogen-carbon medium on the structure, hardness and wear resistance of surface diffusion layers.
Methods. The study of nitrocementation was carried out on samples of improved chromium-molybdenum-vanadium steel 30X3MF (0.38% C; 2.7% Cr; 0.47% Mn; 0.27% Mo; 0.14% V). Nitrocementation was carried out in a paste-like medium consisting of amorphous carbon (carbon black DG 100) - 80% and potassium ferrogenide KuFe(CN)6 – 20%. Nitrocementation was carried out in a shaft laboratory furnace SSHOL-10/11 with automatic temperature control. The hardness of the samples was measured on a TP-2 (Rockwell) hardness tester, microhardness was measured on a PMT-3 microhardness meter. A metallographic optical microscope POLYLAB ML-02 and an electronic scanning microscope QUANTA 3D 200i were used for the analysis. Wear resistance tests of 30X3MF nitrocemented steel samples were carried out on a standard SMC-2 friction machine.
Results. The results of an experimental study of the nitrocementation of 30X3MF steel in a highly active paste-like medium based on potassium ferrocyanide and amorphous soot on its structure and properties are presented. It is shown that nitrocementation promotes the formation of a large number of high-hard carbonitrides in the diffusion layers, which cause a significant (several times) increase in the wear resistance of steel.
Conclusion. The proposed method of nitrocementation, in our opinion, will be very effective for increasing the durability of parts made of improved 30X3MF steel and the like, working at increased power loads in combination with abrasive wear.
About the Authors
V. I. KolmykovRussian Federation
Valery I. Kolmykov, Dr. of Sci. (Engineering), Professor of the Department of Materials Technology and Transport
50 Let Oktyabrya str. 94, Kursk 305040
R. Y. Kostin
Russian Federation
Roman Y. Kostin, Post-Graduate Student of the Department of Materials Technology and Transport
50 Let Oktyabrya str. 94, Kursk 305040
Yu. S. Vorobyev
Russian Federation
Yunis S. Vorobyev, Undergraduate of the Department of Materials Technology and Transport
50 Let Oktyabrya str. 94, Kursk 305040
D. V. Kolmykov
Russian Federation
Denis V. Kolmykov, Can. of Sci. (Engineering), Associate Professor of the Department of General Technical Disciplines and Life Safety
Radishchev str. 33, Kursk 305000
References
1. Kolmykov V. I., Cherniavsky D. A., Kolmykov D. V. [Investigation of the saturating capacity of the paste based on relatoseroticos potassium]. Materialy i uprochnyayushchie tekhnologii – 2006. Sbornik materialov XIII Rossiiskoi nauchno-tekhnicheskoi konferentsii s mezhdunarodnym uchastiem [Materials and hardening technology – 2006: collection of materials]; ed. by V. N. Gadalov. Kursk, Kursk St. Tech. Univ. Publ., 2006, pp. 146–154. (In Russ.)
2. Kolmykov V. I., Tutov N. D., Nikulin A. A., Kolmykov D. V. [Development and investigation of a highly saturated environment for nitrocarburizing at low and high temperatures]. Materialy i uprochnyayushchie tekhnologii – 2008. Sbornik materialov XV Rossiiskoi nauchno-tekhnicheskoi konferentsii s mezhdunarodnym uchastiem [Materials and hardening technologies – 2008. Collection of materials of the XV Russian Scientific and Technical Conference with international participation]; ed. by V. N. Gadalov. Kursk, Kursk St. Tech. Univ. Publ., 2008, pp. 145–147. (In Russ.)
3. Arzamasov V. B., Volchkov A. N., Golovin V. A. Materialovedenie i tekhnologiya konstruktsionnykh materialov [Materials science and technology of structural materials]. Moscow, Academy Publ., 2011. 448 p.
4. Kostin N. A., Kolmykov V. I., Trusova E. V., Kolmykov D. V. Sposob nitrotsementatsii detalei iz shtampovykh stalei [Method of nitrocementation of stamped steel parts]. Patent RF, no. 2501884, 2013.
5. Kolmykov V. I., Roslyakov I. N. Termodinamicheskie usloviya obrazovaniya poverkhnostnykh sloev pri nauglerozhivanii khromomargantsevykh stalei [Thermodynamic conditions of formation of surface layers during carburization of chromium-manganese steels]. Uprochnyayushchie tekhnologii i pokrytiya = Hardening technologies and coatings, 2009, no. 4, pp. 3–5.
6. Gurland J. Razrushenie kompozitov s dispersnymi chastitsami v metallicheskoi matritse [Destruction of composites with dispersed particles in a metal matrix]. Razrushenie i ustalost' [Destruction and fatigue]; ed. by L. Brautman. Moscow, Mir Publ., 1978, pp. 58–105.
7. Chernyavsky D. A. Povyshenie ekspluatatsionnykh kharakteristik zheleznykh elektroliticheskikh pokrytii nitrotsementatsiei. Diss. kand. tekhn. nauk [Improving the performance characteristics of iron electrolytic coatings by nitrocementation. Cand. eng. sci. diss.]. Kursk, 2007. 160 p.
8. Grashkov S. A., Kolmykov V. I. Povyshenie iznosostoikosti stali KhVG dlya detalei toplivnoi apparatury dizelei metodom nitrotsementatsii [Increasing the wear resistance of HVG steel for diesel fuel equipment parts by nitrocementation method]. Izvestiya Yugo-Zapadnogo gosudarstvennogo universiteta. Seriya: Tekhnika i tekhnologii = Proceedings of the Southwest State University. Series: Engineering and Technology, 2020, vol. 10, no. 1, pp. 43–56.
9. Pikalov S. V., Kolmykov V. I., Salnikov V. G., Kirichenko A. A. Karbidoobrazovanie v margantsovistykh stalyakh pri tsementatsii [Carbide formation in manganese steels during cementation]. Zagotovitel'nye proizvodstva v mashinostroenii [Procurement production in mechanical engineering], 2010, no. 7, pp. 37–40.
10. Nikulin A. A. Uprochnenie vysokokhromistykh stalei i pokrytii khimiko-termicheskoi obrabotkoi dlya povysheniya stoikosti v usloviyakh korrozionno-mekhanicheskogo iznashivaniya. Diss. kand. tekhn. nauk [Hardening of high-chromium steels and coatings by chemical-thermal treatment to increase resistance under conditions of corrosion-mechanical wear. Cand. eng. sci. diss.]. Kursk, 2009. 149 p.
11. Przhenosil B. Nitrotsementatsiya [Nitrocementation]. Moscow, Mashinostroenie Publ., 1969. 212 p.
12. Kolmykov V. I., Ziborova T. N., Zhosanov A. A. Povyshenie predela vynoslivosti stali 42KhMFA dlya kolenchatykh valov avtomobil'nykh dvigatelei nizkotemperaturnoi tsementatsiei [Increasing the endurance limit of 42KHMFA steel for crankshafts of automobile engines by low-temperature cementation]. Izvestiya Yugo-Zapadnogo gosudarstvennogo universiteta. Seriya: Tekhnika i tekhnologii = Proceedings of the Southwest State University. Series: Engineering and Technology, 2013, no. 3, pp. 12–15.
13. Serebrovsky V. V., Serebrovsky V. I., Alyabyeva T. V., Bogomolov S. A. Primenenie nitrotsementatsii dlya uprochneniya detalei mashin [Application of nitrocementation for hardening of machine parts]. Izvestiya Yugo-Zapadnogo gosudarstvennogo universiteta. Seriya: Upravlenie, vychislitel'naya tekhnika, informatika. Meditsinskoe priborostroenie. Proce- edings of the Southwest State University = Series: Management, Computer engineering, Computer science. Medical instrumentation, 2012, no 2, pt. 2, pp. 10–12.
14. Vertakova Yu., Plotnikov V. Innovative and industrial development: specifics of interrelation. Ekonomichny chasopis-XXI, 2016, vol. 156, no. 1-2, pp. 37–40.
15. Sharifullin S. N., Topolyansky P. A., Ermakov S. A., Topolyansky A. P. Finishnoe plazmennoe uprochnenie i vosstanovlenie detalei toplivnoi apparatury [Finishing plasma har- dening and restoration of fuel equipment parts]. Metalloobrabotka = Metalworking, 2018, no. 4, pp. 28–39.
16. Kolmykov V. I., Gorozhankin V. V., Bedin V. V., Romanenko D. N. Prognozirovanie abrazivnoi iznosostoikosti dvukhfaznykh struktur v metallicheskikh kompozitakh [Prediction of abrasive wear resistance of two-phase structures in metal composites]. Zagotovitel'nye proizvodstva v mashinostroenii = Procurement production in mechanical engineering, 2013, no. 5, pp. 40–42.
17. Kolmykov V. I., Kolmykov D. V., Vorobyov S. V., Pikalov S. V. [Conditions of formation of carbide-containing wear-resistant layers during cementation of steels]. Materialy i uprochnyayushchie tekhnologii-2009. Sbornik materialov XVI Rossiiskoi nauchno-tekhnicheskoi konferentsii s mezhdunarodnym uchastiem [Materials and hardening technologies-2009. Collection of materials of the XVI Russian Scientific and Technical Conference with international participation]; ed. by V. N. Gadalov. Kursk, Kursk. St. Techn. Univ. Publ., 2009, pp. 33–40. (In Russ.)
18. Serebrovsky V. Povyshenie iznosostoikosti stal'nykh detalei nizkotemperaturnoi nitrotsementatsiei [Increasing the wear resistance of steel parts by low-temperature nitrocementation]. Mezhdunarodnyi sel'skokhozyaistvennyi zhurnal = International Agricultural Journal, 2008, no. 2, pp. 62a–64.
19. Bedin V. V., Kolmykov V. I. Ob effektivnosti khimiko-termicheskoi obrabotki detalei mashin, vosstanovlennykh naplavkoi v srede zashchitnykh gazov [The effectiveness of chemical-thermal processing machinery parts, restored welding in shielding gases]. Vestnik Kurskoi gosudarstvennoi sel'skokhozyaistvennoi akademii = Bulletin of the Kursk state agricultural Academy, 2011, no. 6, pp. 77–79.
20. Kolmykov V. I., Gorozhankin V. V., Romanenko D. N. Prognozirovanie abrazivnoi iznosostoikosti dvukhfaznykh struktur v metallicheskikh kompozitakh [Prediction of abrasive wear resistance of two-phase structures in metal composites]. Zagotovitel'nye proizvodstva v mashinostroenii = Blank production in mechanical engineering, 2013, no. 5, pp. 40–42.
Review
For citations:
Kolmykov V.I., Kostin R.Y., Vorobyev Yu.S., Kolmykov D.V. Improving the Performance Properties of Chromium-Molybdenum- Vanadium steel 30X3MF for Automotive Parts by Nitrocementation in an Active Medium. Proceedings of the Southwest State University. Series: Engineering and Technology. 2022;12(1):41-53. (In Russ.) https://doi.org/10.21869/2223-1528-2022-12-1-41-53