Fire resistance of textile materials treated with flame retardant based on electroerosive Aluminum hydroxide powder
https://doi.org/10.21869/2223-1528-2024-14-4-71-80
Abstract
The purpose of this work was to study the fire resistance of technical materials treated with flame retardants based on electroerosion powder of Aluminum hydroxide.
Methods. Aluminum metal wastes of the AD0E brand were dispersed in distilled water at a loading weight of 250 g at an experimental installation. The resulting electroerosive aluminum powder was studied by various methods. The microanalysis was performed on a QUANTA 600 FEG microscope. The phase composition was studied using a Rigaku Ultima IV diffractometer. The fire resistance of the treated fabric was studied according to the following method: a strip of fabric 5 cm wide and 10 cm long was suspended in an upright position by one end in a tripod clamp (the other end remains hanging freely). The flame of an alcohol burner was placed under the lower end of the sample for 12 seconds (according to a stopwatch). After the specified time, the flame of the burner was removed and the burning and smoldering time of the sample was noted after the flame ceased to act. Gorenje After the end of the experiment, the area of the charred part of the sample was measured.
Results. Experimental studies of the fire resistance of textile materials treated with flame retardants have shown high efficiency of using an electroerosive aluminum hydroxide powder for these purposes. Aluminum hydroxide powder was obtained in distilled water from electrical aluminum metal waste. The peculiarity of the use of the obtained aluminum hydroxide is due to the fact that it provides a difficult-to-ignite fabric, reduces the ability of the material to ignite, localizes the flame; provides a long-term flame retardant and at the same time antiseptic effect; treated fabrics are odorless, harmless to humans and animals; consumption for impregnating fabrics: 100-250 g/m2, depending on the density of the fabric.
Conclusion. The effectiveness of flame retardants based on electroerosive Aluminum hydroxide powder is confirmed by the fact that cheap metal waste and progressive environmentally friendly (without wastewater and emissions), low- energy technology (up to 5 kWh/kg) are used for its production.
About the Authors
A. E. AgeevaRussian Federation
Anna E. Ageeva - Student, Southwest State University.
50 let Oktyabrya Str. 94, Kursk 305040
E. V. Ageeva
Russian Federation
Ekaterina V. Ageeva - Doctor of Sciences (Engineering), Associate Professor, Professor of the Department of Technology of Materials and Transport, Southwest State University.
50 let Oktyabrya Str. 94, Kursk 305040
References
1. Dayronas M.V., Kurbatov V.L., Shumilova E.Y. Effectiveness of modern flame retardants. Universitetskaya nauka = University science. 2024;(1):45-52. (In Russ.) EDN ESOHUZ
2. Trubachev S.A., Paletsky A.A., Sagitov A.R., Kulikov I.V., Sosnin E.A., Shmakov A.G. The effect of flame retardants additives on the flammability and smoke formation of epoxy resin-based plastics. Khimicheskaya fizika i mezoskopiya = Chemical Physics and Mesoscopy. 2024;26(3):331- 340. (In Russ.) https://doi.org/10.62669/17270227.2024.3.28, EDN JZRPNJ
3. Spiridonova V.G., Sorokin D.V., Nikiforov A.L., Tsikina O.G. Substantiation of relevant approaches to assessing the fire-hazardous properties of textile materials and methods of fire protection of fabrics of various functional purposes. Ovremennye problemy grazhdanskoi zashchity = Modern problems of civil protection. 2023;(2):125-132. (In Russ.) EDN UCBLRB
4. Novikov E.P., Podanov V.O., Ageeva A.E. Investigation of the phase composition of the electrocorunde powder obtained by electrodispersion of AD0E alloy waste. In: Sovremennye innovatsii v nauke i tekhnike: sbornik nauchnykh statei 12-i Vserossiiskoi nauchno-tekhnicheskoi konferentsii s mezhdunarodnym uchastiem = Modern innovations in science and technology: collection of scientific articles of the 12th All-Russian scientific and technical conference with international participation. Kursk: Universitetskaya kniga; 2022. P. 186-190. (In Russ.) EDN JBOFHL
5. Ageeva A.E. Flame retardant for textile materials based on electroerosive Aluminum hydroxide powder. In: Sovremennye problemy i napravleniya razvitiya metallovedeniya i termicheskoi obrabotki metallov i splavov: sbornik nauchnykh statei 3-i Mezhdunarodnoi nauchno-prakticheskoi konferentsii, posvyashchennoi pamyati akademika A.A. Baikova = Modern problems and directions of development of metallurgy and thermal processing of metals and alloys: collection of scientific articles of the 3rd International scientific and practical conference dedicated to the memory of academician A.A. Baykov. Kursk: Universitetskaya kniga; 2022. P. 29-35. (In Russ.) EDN KDAYDV
6. Kuzmina N.N., Tsirkina O.G. Formaldehyde-containing flame retardants in the finishing of cellulose-containing fabrics. Molodye uchenye - razvitiyu natsional'noi tekhnologicheskoi initsiativy (POISK) = Young scientists - development of the National Technological Initiative (SEARCH). 2024;(1):511-512. (In Russ.) EDN QYPKYX
7. Ismailov R.I., Eshmukhamedov U.M., Khaidarov I.N., Ismailova R.M. Technology of obtaining and studying the properties of flame retardants based on epichlorohydrin with nitrogen-containing compounds for polyacrylonitrile fibers. Izvestiya vysshikh uchebnykh zavedenii. Tekhnologiya tekstil'noi promyshlennosti = Proceedings of higher educational institutions. Textile Industry Technology. 2023;(3):162-168. https://doi.org/10.47367/0021-3497_2023_3_162. (In Russ.) EDN LLUKSI
8. Matveenko Yu.V., Shatilov Yu.S., Lukyanov A.S., Ignatovich Zh.V., Rogachev A.A., Agabekov V.E. Improvement of flame-retardant properties of fabrics based on polyoxadiene fibers by finishing with organophosphorus flame retardants. Chrezvychainye situatsii: preduprezhdenie i likvidatsiya = Emergency situations: prevention and elimination. 2023;(2):116-119. (In Russ.) EDN BEKBVB.
9. Gadalov V.N., Salnikov V.G., Ageev E.V., Romanenko D.N. Metallography of metals, powder materials and coatings obtained by electric spark methods. Moscow: Infra-M; 2011. 468 p. (In Russ.) EDN SDQRQT.
10. Ageev E.V., Latypov R.A., Ageeva E.V., Davydov A.A. Preparation and research of powders from waste of tungsten-containing hard alloys by electroerosive dispersion. Kursk: IP Gorokhov A.A.; 2013. 200 p. (In Russ.) EDN RZROAL.
11. Latypov R.A., Ageev E.V., Ageeva E.V., Novikov E.P. Investigation of Aluminum powder obtained by electroerosion dispersion in distilled water. Vse materialy. Entsiklopedicheskii spravochnik = All materials. Encyclopedic reference book. 2016;(4):19-22. (In Russ.) EDN VSKPXR
12. Ageev E.V., Gorokhov A.A., Altukhov A.Yu., Shcherbakov A.V., Khardikov S.V. X-ray spectral microanalysis of nichrome powder obtained by the method of electroerosive dispersion in a kerosene medium. Izvestiya Yugo-Zapadnogo gosudarstvennogo universiteta = Proceedings of the Southwest State University. 2016;(1):26-31. (In Russ.) EDN VXDVNX
13. Ageev E.V., Ageeva E.V., Vorobyov E.A. Granulometric and phase compositions of powder obtained from tungsten-containing waste of tool materials by electroerosive dispersion in kerosene. Uprochnyayushchie tekhnologii i pokrytiya = Hardening technologies and coatings. 2014;(4):11-14. (In Russ.) EDN SAMGBH
14. Ageeva A.E., Khmelevskaya A.G. Cotton: all about fabric. In: Problemy razvitiya sovremen- nogo obshchestva: sbornik nauchnykh statei 9-i Vserossiiskoi natsional'noi nauchno-prakticheskoi konferentsii = Problems of development of modern society: collection of scientific articles of the 9th All-Russian national scientific and practical conference. Vol. 3. Kursk: Universitetskaya kniga; 2024. P. 593-596. EDN GJPULZ
15. Ageeva A.E., Khmelevskaya A.G. Synthetics: all about fabric. Molodezh' i nauka: shag k uspekhu: sbornik nauchnykh statei 7-i Vserossiiskoi nauchnoi konferentsii perspektivnykh razrabotok molodykh uchenykh = Youth and science: a step to success : collection of scientific articles of the 7th All-Russian Scientific Conference of promising developments of young scientists. Kursk: Universi- tetskaya kniga; 2024. P. 284-287. EDN MVTOIT
16. Reva O.V., Bogdanova V.V., Lukyanov A.S., Moiseyuk S.Yu. Development of methods of fire resistance to cellulose and mixed fabrics for protective clothing. Chrezvychainye situatsii: preduprezhdenie i likvidatsiya = Emergency situations: prevention and liquidation. 2020;(1):138-149. (In Russ.) EDN OUNJMB
17. Nurkulov F.N., Raupov A.R., Jalilov A.T. Increasing the fire resistance of textile fabrics based on cellulose. Universum: tekhnicheskie nauki = Universum: technical sciences. 2021;(7-2):79-82. (In Russ.) https://doi.org/10.32743/UniTech.2021.88.7.12111, EDN BBPUNM
18. Shinkareva E.V., Simash N.A. Aqueous vermiculite dispersion for increasing the fire resistance of fabrics in the texture of a fiberglass matrix. Lakokrasochnye materialy i ikh primenenie = Paint and varnish materials and their application. 2022;(10):26-31. (In Russ.) EDN CAJBOI
19. Reva O.V., Zarubitskaya T.I. Giving permanent fire resistance to cotton fabrics and fibers by chemo-binding inorganic flame-retardant compounds to their surface. Chrezvychainye situatsii: preduprezhdenie i likvidatsiya = Emergency situations: prevention and elimination. 2016;(1):77-85. (In Russ.) EDN YSPYOJ
Review
For citations:
Ageeva A.E., Ageeva E.V. Fire resistance of textile materials treated with flame retardant based on electroerosive Aluminum hydroxide powder. Proceedings of the Southwest State University. Series: Engineering and Technology. 2024;14(4):71-80. (In Russ.) https://doi.org/10.21869/2223-1528-2024-14-4-71-80