Recognition of Silver Nanoparticles on Polyester Fibers in the Analytical Evaluation of the Intersection of Distribution Ellipses by Polarization Raman Spectra

The purpose of the work is to increasing the resolution of Raman spectroscopy using the transformation of multidimensional vector-matrix correlation mathematical models for the identification of silver nanoparticles in nanostructured biological objects under conditions of information uncertainty.

Metods. The research methods are based on the mathematical apparatus of regression, multidimensional vectormatrix analysis, probability theory, namely, for the implementation of scientific tasks in this study, they are used: Raman spectroscopy; the physical effect of giant Raman scattering (SERS); statistical modeling of the random process of changing the experimental parameters of silver nanoparticles together with autocorrelation functions and interdependent parameters on the correlation matrix; vector-matrix method for modeling the equivalent radius of ellipses of the distribution of two-dimensional correlation distributions in solving the equations of recognition of silver nanoparticles on the multidimensional components of Raman spectra. Numerical implementation of mathematical models is carried out on a PC in the MathCAD Enterprise Edition 15 environment. 

Results. In the course of the study, the reliability of recognition of colloidal silver nanoparticles on polyester fibers was evaluated by the multidimensional correlation components of the Raman spectra when controlled by the polarization characteristics. It is shown that the proposed method of recognition of silver nanoparticles on the surface of textile materials gives a significant advantage in assessing the reliability of determining the modes of deposition of silver nanoparticles on fibers.

Metods. A method of mathematical modeling for the identification and control of silver nanoparticles on the surface of textile materials is proposed; a vector-matrix model of the equivalent ellipse radius of the distribution of twodimensional correlation distributions is obtained for solving the equations of recognition of silver nanoparticles by multidimensional correlation components of Raman spectra; a software implementation of multidimensional polarization correlation methods for increasing the reliability of identification of silver nanoparticles is developed. 

1. Schedin F., Lidorikis E., Lombardo A., Kravets V. G., Geim A. K., Grigorenko A. N., Novoselov K. S., Ferrari A. C. Surface enhanced raman spectroscopy of graphene. ACS Nano. 2010, vol. 4. no. 10, рр. 5617–5626.

2. Moore T. J., Moody A. S., Payne T. D., Sarabia G. M., Daniel A. R., Sharma B. In vitro and in vivo SERS Biosensing for Disease Diagnosis. Biosensors, 2018, vol. 8, no. 2. http://doi.org/10.3390/bios8020046.

3. Xiang Yu., Yang H., Guo Х., Wu Y.,Ying Ye, Wen Y., Yang H. Surface enhanced Raman detection of the colon cancer biomarker cytidine by using magnetized nanoparticles of the type Fe3O4/Au/Ag. Microchimica Acta, 2018, vol. 185. http://doi.org/10.1007/s00604017-2666-5.

4. Kovalenko A. V., Plakhtii Ye. G., Khmelenko O. V. Research of Photoluminescence spectra of ZnSXSe1 – X:Mn nanocrystals obtained by method of self-propagating hightemperature synthesis. Journal of Nano- and Electronic Phisics, 2019, vol. 11, no. 4, рр. 04031-1–04031-5.

5. Crucho C. I. C. , Barrosb M. T. Polymeric nanoparticles: A study on the preparation variables and characterization methods. Materials Science and Engineering: C, 2017, vol. 80, рр. 771–784.

6. Yamanova R. R., Nikolaenko G. R. O primenenii nanochastits serebra v legkoi promyshlennosti [On the use of silver nanoparticles in light industry]. Vestnik Kazanskogo tekhnologicheskogo universiteta = Bulletin of the Kazan Technological University, 2013, no. 22, pp. 39–41.

7. Kuznetsova S. A., Krasnova T. Yu. Primenenie nanotekhnologii v tekstil'noi promyshlennosti [Application of nanotechnologies in the textile industry]. Vestnik molodykh uchenykh Sankt-Peterburgskogo gosudarstvennogo universiteta tekhnologii i dizaina = Vestnik of St. Petersburg State University of Technology and Design, 2017, no. 4, рр. 42–45.

8. Vasilyeva N. G. Nanotekhnologii v tekstil'noi promyshlennosti [Nanotechnologies in the textile industry]. Vestnik Kazanskogo tekhnologicheskogo universiteta = Bulletin of the Kazan Technological University, 2011, no. 8, pp. 358–360.

9. Bukina Yu. A., Sergeeva E. A. Poluchenie antibakterial'nykh tekstil'nykh materialov na osnove nanochastits serebra posredstvom modifikatsii poverkhnosti tekstilya neravnovesnoi nizkotemperaturnoi plazmoi [Preparation of antibacterial textile materials based on silver nanoparticles by modifying the surface of textiles with nonequilibrium lowtemperature plasma]. Vestnik Kazanskogo tekhnologicheskogo universiteta = Bulletin of the Kazan Technological University, 2012, no. 7, pp. 125–128.

10. Petrova L. S., Lipina A. A., Zaitseva A. O., Odintsova O. I. Ispol'zovanie nanochastits serebra dlya pridaniya tekstil'nym materialam bakteritsidnykh svoistv [The use of silver nanoparticles to impart bactericidal properties to textile materials]. Izvestiya vysshikh uchebnykh zavedenii. tekhnologiya tekstil'noi promyshlennosti = Proceedings of Higher Educational Institutions. Textile Industry Technology, 2018, no. 6(378), pp. 105–109.

11. Odintsova O. I., Petrova L. S., Antonova A. S., Kozlova O. V. Primenenie nanochastits serebra dlya modifikatsii svoistv tekstil'nykh materialov [Application of silver nanoparticles for modifying the properties of textile materials]. Vestnik Tekhnologicheskogo universiteta Tadzhikistana = Bulletin of the Technological University of Tajikistan, 2019, no. 2(37), pp. 19–22.

12. Antonova M. V., Krasina I. V., Ilyushina S. V. Metody pridaniya antibakterial'nykh svoistv tekstil'nym voloknam. Obzor [Methods of giving antibacterial properties to textile fibers. Obzor]. Vestnik Kazanskogo tekhnologicheskogo universiteta = Bulletin of the Kazan Technological University, 2014, vol. 17, no. 18, pp. 56–63.

13. Esirkepova A. M., Akhmetova G. Zh., Sadykov A. S., Abilkasym A. B., Ashirbaye- va C. B. Vliyanie innovatsionnykh tekhnologii i materialov na razvitie tekstil'noi promyshlennosti [Influence of innovative technologies and materials on the development of the textile industry]. Izvestiya vysshikh uchebnykh zavedenii. Tekhnologiya tekstil'noi promyshlennosti = Proceedings of Higher Educational Institutions. Textile Industry Technology, 2020, no. 3 (387), pp. 52–60.

14. Khammatova V. V. Metod nanomodifitsirovaniya natural'nykh tekstil'nykh materialov kolloidnym rastvorom nanochastits serebra [Method of nanomodification of natural textile materials with a colloidal solution of silver nanoparticles]. Izvestiya vysshikh uchebnykh zavedenii. Tekhnologiya tekstil'noi promyshlennosti = Proceedings of Higher Educational Institutions. Textile Industry Technology, 2015, no. 6 (360), pp. 103–108.

15. Torshin A. S. Razrabotka nanotekhnologicheskikh metodov pridaniya tekstil'nym materialam biotsidnykh svoistv i zashchity ot sverkhvysokochastotnogo izlucheniya. Diss. kand. тechn. nauk [Development of nanotechnological methods for giving textile materials biocidal properties and protection from ultrahigh-frequency radiation. Diss. cand. eng. sci.]. Moscow, 2016. 158 p.

16. Khammatova V. V., Yumenev K. E. Provedenie issledovanii mikrostruktury obraztsov nanomodifitsirovannykh tekstil'nykh materialov dlya spetsial'noi odezhdy metodami mikroskopii [Conducting studies of the microstructure of samples of nanomodified textile materials for special clothing by microscopy methods]. Izvestiya vysshikh uchebnykh zavedenii. Tekhnologiya tekstil'noi promyshlennosti = Proceedings of Higher Educational Institutions. Textile Industry Technology, 2016, no. 5 (365), pp. 84–89.

17. Emelyanov V. M., Dobrovolskaya T. A., Emelyanov V. V., Orlov E. Yu., Butov K. V. Primenenie metodov Ramanovskoi spektroskopii dlya vyyavleniya nanochastits zolota na poliefirnykh voloknakh [Application of Raman spectroscopy methods for detecting gold nanoparticles on polyester fibers]. Izvestiya Yugo-Zapadnogo gosudarstvennogo universiteta Se-riya: Fizika i khimiya = Proceedings of the Southwest State University. Series: Physics and Chemistry, 2013, no. 2, pp. 37–43.

18. Emelyanov V. M., Dobrovolskaya T. A., Danilova S. A., Emelyanov V. V., Bu- tov K. V. Vydelenie fonovykh sostavlyayushchikh ramanovskikh spektrov dlya kontrolya nanochastits zolota na poverkhnosti tekstil'nykh materialov [Isolation of background components of Raman spectra for the control of gold nanoparticles on the surface of textile materials]. Izvestiya Yugo-Zapadnogo gosudarstvennogo universiteta. Seriya: Fizika i khimiya = Proceedings of the Southwest State University. Series: Physics and Chemistry, 2014, no. 1, pp. 8–15.

19. Emelyanov V. M., Dobrovolskaya T. A., Emelyanov V. V. Identifikatsiya nanochastits serebra i zolota na poverkhnosti volokon. Mnogomernoe vektorno-matrichnoe modelirovanie ramanovskikh spektrov tekstil'nykh materialov [Identification of silver and gold nanoparticles on the fiber surface. Multidimensional vector-matrix modeling of Raman spectra of textile materials]. LAP LAMBERT Academic Publishing, 2017. 180 p.

20. Emelyanov V. M., Dobrovolskaya T. A., Emelyanov V. V., Butov K. V. Mnogomernaya korrelyatsionnaya otsenka nalichiya nanochastits serebra na poliefirnykh voloknakh po polyarizatsionnym ramanovskim spektram [Multidimensional correlation estimation of the presence of silver nanoparticles on polyester fibers by polarization Raman spectra]. Fundamental'nye issledovaniya = Basic research, 2015, no. 8, pt. 2, pp. 261–267.

21. Emelyanov V. M., Dobrovolskaya T. A., Emelyanov V. V., Butov K. V. Raspoznavanie nanochastits serebra na tekstil'nykh materialakh po polyarizatsionnym ramanovskim spektram na osnove provedeniya vektorno-matrichnogo modelirovaniya [Recognition of silver nanoparticles on textile materials by polarization Raman spectra based on vector-matrix modeling]. Sovremennye naukoemkie tekhnologii = Modern High-Tech Technologies, 2016, no. 9–1, pp. 41–45.

22. Emelyanov V. M., Dobrovolskaya T. A., Emelyanov V. V. Komp'yuternoe modelirovanie ramanovskikh spektrov tekstil'nykh materialov pri nanesenii na nikh nanochastits serebra, zolota [Computer modeling of Raman spectra of textile materials when silver and gold nanoparticles are applied to them]. Fundamental'nye issledovaniya = Basic research, 2017, no. 10, pt. 1, pp. 7–12.