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Structure and properties of finely dispersed Cobalt powder from Cobalt metal waste of the K1Au brand

https://doi.org/10.21869/2223-1528-2025-15-3-8-18

Abstract

   Purpose. Investigation of the relationships between the composition, structure and properties of the initial Cobalt metal waste and the powder obtained by crushing these wastes by electric erosion in liquid dielectrics.

   Methods. Finely dispersed powder from Cobalt metal waste of the K1Au brand was obtained on an original patented installation in a liquid dielectric medium - distilled water by electric erosion. The pieces of the metal tube were loaded into a reactor filled with a working fluid, and a pulse voltage from a pulse generator was applied through electrodes made of the same metal tube. When the energy was reached to penetrate the liquid dielectric, electrical discharges occurred between the pieces of metal waste to form powder microparticles, which were further investigated by various methods to determine their granulometric, chemical, and phase compositions using modern research equipment.

   Results. It was found that the resulting electroerosive Cobalt powder has dimensions ranging from 0.45 microns to 38.72 microns and contains oxygen on the surface. The phase analysis showed the presence of only one phase in the particles of electroerosive cobalt powder – the Cobalt phase. From the analysis of the particle shape and morphology, it was found that the obtained parts mostly have the shape of a sphere with an average size of 8.6 microns and lumps of agglomerates consisting of finely dispersed particles.

   Conclusion. The obtained research results can be used to develop a new hard alloy using waste materials of expensive cobalt raw materials by the method of electroerosion dispersion with subsequent improvement and optimization of the composition and structure of the alloy.

About the Authors

E. V. Ageeva
Southwest State University
Россия

Ekaterina V. Ageeva, Doctor of Sciences (Engineering), Professor, Professor of the Department

Department of Materials Technology and Transport

305040; 50 let Oktyabrya Str. 94; Kursk



O. G. Loktionova
Southwest State University
Россия

Oksana G. Loktionova, Doctor of Sciences (Engineering), Professor

305040; 50 let Oktyabrya Str. 94; Kursk



D. A. Ulitin
Southwest State University
Россия

Dmitry A. Ulitin, Postgraduate Student

Department of Technology of Materials and Transport

305040; 50 let Oktyabrya Str. 94; Kursk



I. V. Vornacheva
Southwest State University
Россия

Irina V. Vornacheva, Candidate of Technical Sciences, Associate Professor, Acting Head of the Department

Department of Electric Power Engineering and Electrical Engineering

305040; 50 let Oktyabrya Str. 94; Kursk



References

1. Walter A.I., Kozhevnikov L.S. Comparison of the structure and mechanical properties of tungsten heavy alloy VNZH95 during solid-phase and liquid-phase sintering. Epokha nauki = The age of science. 2024;(37):27-30. (In Russ.) EDN: VSPMHY.

2. Grigorieva T.F., Dyachkova L.N., Ilyushenko A.F., Osipov V.A., Voronikov S.V., Devyatkina E.T. Tungsten-based pseudo-alloys for protection against ionizing radiation obtained using mechanically activated precursors. In: Tekhnologicheskoe obespechenie mashinostroitel'nykh proizvodstv : sbornik statei Mezhdunarodnoi nauchno-tekhnicheskoi konferentsii = Technological support of machine-building products : collection of articles of the International scientific and technical conference. Mogilev: Belorussko-Rossiiskii un-t; 2024. P. 6-12. (In Russ.) EDN: XYKGBK.

3. Ageeva E.V., Loktionova O.G., Ulitin D.A., Ageeva A.E. Structure and properties of powders obtained by electrodispersion of pure nickel metal waste in distilled water. Izvestiya Yugo-Zapadnogo gosudarstvennogo universiteta. Seriya: Tekhnika i tekhnologii = Proceedings of the Southwest State University. Series: Engineering and Technologies. 2024;14(3):8-18. (In Russ.) doi: 10.21869/ 2223-1528-2024-14-3-8-18. EDN: EIEGZE.

4. Trofimenko N.N., Efimochkin I.Yu., Dvoretskov R.M., Batienkov R.V. Production of fine-grained hard alloys of the WC-Co system (review). Trudy VIAM = Proceedings of VIAM. 2020;(1):92-100. (In Russ.) doi: 10.18577/2307-6046-2020-0-1-92-100. EDN: TVMXDB.

5. Kablov E.N., Lukina E.A., Zavodov A.V., Efimochkin I.Yu. Formation of the structure of hard alloys based on the WC-Co system with submicron grain in the presence of inhibitory additives. Trudy VIAM = Proceedings of VIAM. 2020;(4-5):89-99. (In Russ.) doi: 10.18577/2307-6046-2020-0-45-89-99. EDN: FUDTAU.

6. Sokolov A.G., Bobylev E.E., Plomodialo R.L. The effect of cementation on the structure and properties of functional diffusion coatings based on Titanium carbide on hard alloys such as TC and VC. Pis'ma o materialakh = Letters on materials. 2020;10(4):410-415. (In Russ.) doi: 10.22226/2410-3535-2020-4-410-415. EDN: IVQKLP.

7. Mazalov I.S., Mazalov P.B., Sukhov D.I., Suljanova E.A. The influence of the parameters of hot isostatic pressing on the structure and properties of Cobalt-based alloys obtained by selective laser fusion. Aviatsionnye materialy i tekhnologii = Aviation Materials and Technologies. 2021;(2):3-14. (In Russ.) doi: 10.18577/2713-0193-2021-0-2-3-14. EDN: ZOPGKU.

8. Dvornik M.I., Mikhailenko E.A. Creation of ultrafine-grained WC-15Co hard alloy from powder obtained by electroerosion dispersion of VK15 alloy waste in water. Izvestiya vysshikh uchebnykh zavedenii. Poroshkovaya metallurgiya i funktsional'nye pokrytiya = Powder Metallurgy and Functional Coatings. 2020;(3):4-16. (In Russ.) doi: 10.17073/1997-308X-2020-3-4-16. EDN: HUEWDA.

9. Krinitsyn M.G., Pervikov A.S., Toropkov N.E., Lerner M.I. Investigation of powder materials of W-CU pseudo-alloy. In: Orlov M.Yu. (ed.) Aktual'nye problemy sovremennoi mekhaniki sploshnykh sred i nebesnoi mekhaniki – 2021 : materialy XI Vserossiiskoi nauchnoi konferentsii s mezhdunarodnym uchastiem = Actual problems of modern continuum mechanics and celestial mechanics - 2021 : materials of the XI All-Russian scientific conference with international participation. Tomsk, 2022. P. 373-377. (In Russ.) EDN: QLPREX.

10. Mazalov P.B., Sukhov D.I., Sulyanova E.A., Mazalov I.S. Heat-resistant Cobalt-based alloys. Aviatsionnye materialy i tekhnologii = Aviation Materials and Technologies. 2021;(3):3-10. (In Russ.) doi: 10.18577/2713-0193-2021-0-3-3-10. EDN: JWUOZX.

11. Akhmetov A.S., Eremeeva Zh.V. Study of the nature of the diffusion alloying of a mixture for powdered high-speed steel. Materialovedenie = Materials Science. 2021;(6):13-16. (In Russ.) doi: 10.31044/1684-579X-2021-0-6-13-16. EDN: HITHLB.

12. Gryaznov M., Samokhin A., Chuvildeev V. Obtaining a composite sheet of the W-Ni-Fe system with a spherical particle shape and exploring the possibility of its use in layered laser fusion technology. Fizika i khimiya obrabotki materialov = Physics and Chemistry of Materials Processing. 2022;(3):54-66. (In Russ.) EDN: UERDWV.

13. Sharipzyanova G.H., Eremeeva J.V. Research of technology of production of hard alloy materials. Izvestiya Tul'skogo gosudarstvennogo universiteta. Nauki o Zemle = Proceedings of Tula State University. Earth Sciences. 2023;(1-1):360-370. (In Russ.) doi: 10.46689/2218-5194-2023-1-1-360-370. EDN: IQPWOB.

14. Ageev E.V., Semenikhin B. A., Latypov R.A., Anikanov V.I. Installation for the production of nanodisperse powders from conductive materials. Russian Federation patent 2449859. 10 May 2012. 10 p. (In Russ.)

15. Kuznetsova O.G., Levin A.M., Sevostyanov M.A. Modernization of electrochemical processing of heavy tungsten alloys using alternating current. In: Novye materily i perspektivnye tekhnologii. Shestoi Mezhdistsiplinarnyi nauchnyi forum s mezhdunarodnym uchastiem = New materials and promising technologies. The sixth Interdisciplinary scientific forum with international participation. Vol. 2. Moscow: Tsentr nauchno-tekhnicheskikh reshenii; 2020. P. 433-437. (In Russ.) EDN: CHJJXP.

16. Fetisov G.V. X-ray diffraction methods of structural diagnostics of materials: progress and achievements. Uspekhi fizicheskikh nauk = Successes of physical sciences. 2020;190(1):2-36. (In Russ.) EDN: RJBIAY.

17. Dvornik M.I., Vlasova N.M. Comparative analysis of the operational resistance of submicron WC-10Co hard alloy sintered from powder obtained by electroerosion dispersion in oil. Izvestiya vysshikh uchebnykh zavedenii. Poroshkovaya metallurgiya i funktsional'nye pokrytiya = Powder Metallurgy and Functional Coatings. 2023;17(1):75-84. (In Russ.) doi: 10.17073/1997-308X-2023-1-75-84. EDN: ALELTB.

18. Plesovskikh A.Yu., Krylova S.E. Investigation of the structure and properties of a wear-resistant gas-thermal coating with a tungsten content. Frontier Materials & Technologies. 2023;(2):89-101. (In Russ.) EDN: UQIPRW.

19. Chernogor A.V., Blinkov I.V., Belov D.S., Sergevnin V.S., Demirov A.P. The influence of nickel on the composition, structure and properties of Ti-Cr-N coatings. Izvestiya vuzov. Poroshkovaya metallurgiya i funktsional'nye pokrytiya = Powder Metallurgy and Functional Coatings. 2023;17(1):63-74. (In Russ.) doi: 10.17073/1997-308X-2023-1-63-74. EDN: PWHHPO.

20. Latypova G.R., Karpenko N.N., Latypov R.A., Strizheus V.A. Structure and properties of sintered products from powder obtained by electroerosion of steel waste P18. Elektrometallurgiya = Electrometallurgy. 2023;(10):34-39. (In Russ.) doi: 10.31044/1684-5781-2023-0-10-34-39. EDN: SRRHHO.


Review

For citations:


Ageeva E.V., Loktionova O.G., Ulitin D.A., Vornacheva I.V. Structure and properties of finely dispersed Cobalt powder from Cobalt metal waste of the K1Au brand. Proceedings of the Southwest State University. Series: Engineering and Technology. 2025;15(3):8-18. (In Russ.) https://doi.org/10.21869/2223-1528-2025-15-3-8-18

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