Experimental studies of the mechanical characteristics of composite polymer materials based on polypropylene doped with carbon nanotubes
https://doi.org/10.21869/2223-1528-2025-15-2-149-158
Abstract
Research objective. This work considers the issues of using carbon nanotubes as fillers in order to improve the strength properties of polymer materials based on polypropylene, which are used in various industries, oil and gas production, metallurgy, electric power engineering, etc.
Methods. A method for creating a new polymer composite material based on polypropylene with the addition of carbon nanotubes has been developed. Experimental tests of the strength of prototypes made of the "polypropylene-carbon nanotubes" composite were conducted in accordance with GOST 25.601-80 "Calculations and Tests for Strength".
Results. In the course of experimental studies, it was found that ultrasonic exposure of carbon nanotubes with a properly selected solvent and exposure conditions is an important condition for using CNTs as a nano-additive. To obtain a composite granular polymer material by introducing carbon nanotubes, it is most advisable to use a twin-screw extruder with pre-selected temperature regimes in each heating zone and the speed of rotation of the screws. It has been established that the introduction of carbon nanotubes in microquantities (0.2–0.4 wt. %) into the polymer matrix leads to an increase in the maximum allowable load to ~0.03–0.05 kN, the plastic deformation coefficient ~2.2–7.1% and the tensile strength ~1–2.5 N/mm2.
Conclusion. The results obtained allow us to conclude that the use of carbon nanotubes as nanoadditives in the polymer matrix of polypropylene allows us to create special polymers with unique properties without significantly increasing the cost of their production. In addition, the control of the percentage of CNTs allows us to design custom materials with precise control of their properties.
About the Author
L. S. ElbakyanRussian Federation
Lusine S. Elbakyan, Candidate of Sciences (Physics and Mathematics), Associate Professor of Forensic Examination and Physical Materials Science, Institute of Priority Technologies
100 Universitetsky Ave., Volgograd 400062
References
1. Ibrahim K.S. Carbon nanotubes-properties and applications: a review. Carbon Lett. 2013;14(3):131-144.
2. Dyachkov P.N. Carbon nanotubes: structure, properties, applications. Moscow: BINOM. Laboratoriya znanii, 2006. 293 p. (In Russ.).
3. Yeletsky A.V. Carbon nanotubes. Uspekhi fizicheskikh nauk = Physics Uspekhi. 1997;167(9): 945-972. (In Russ.)
4. Shevchenko V.G. Fundamentals of the physics of polymer composite materials. Moscow: Izdvo MGU im. M.V. Lomonosova; 2010. 99 p. (In Russ.)
5. Wing Mai Y., Zhong-Zhen Y. Polymer nanocomposites. Moscow: Tekhnosfera; 2011. 688 p. (In Russ.)
6. Stern T., Marom G. Failure mechanisms and strength of polymer nanocomposites: A brief review. J. Compos. Sci. 2024;8(10):395. https://doi.org/10.3390/jcs8100395.
7. Greene J.P. Automotive plastics and composites. Materials and processing. Elsevier Science & Technology Books; 2021. P. 83-105. https://doi.org/10.1016/C2018-0-03030-3.
8. Campo E.A. Selection of Polymeric Materials. Norwich, NY: William Andrew Publishing. 2008. P. 21-50.
9. Lu D., Huo Y., Jiang Z., Zhong J. Carbon nanotube polymer nanocomposites coated aggregate enabled highly conductive concrete for structural health monitoring. Journal Carbon. 2023;206:340- 350.
10. Spitalsky Z., Tasis D., Papagelis K., Galiotis C. Carbon nanotube–polymer composites: Chemistry, processing, mechanical and electrical properties. Progress in Polymer Science. 2010;35(3):357-401. https://doi.org/10.1016/j.progpolymsci.2009.09.003.
11. Rathinavel S., Priyadharshini K., Dhananjaya Panda. A review on carbon nanotube: An overview of synthesis, properties, functionalization, characterization, and the application. Materials Science and Engineering: B. 2021. Vol. 268. P. 115095. https://doi.org/10.1016/j.mseb.2021.115095.
12. Fenta E.W., Mebratie B.A. Advancements in carbon nanotube-polymer composites: Enhancing properties and applications through advanced manufacturing techniques. Heliyon. 2024;10(16):e36490. https://doi.org/10.1016/j.heliyon.2024.e36490.
13. Jung H., An S.Y., Lim J.S., Kim D. Transparent conductive thin film synthesis based on single-walled carbon nanotubes dispersion containing polymethylmethacrylate binder. Journal of Nanoscience and Nanotechnology. 2011;11(7):6345-6349.
14. Zaporotskova I.V. Carbon and non-carbon nanomaterials and composite structures based on them: structure and electronic properties. Volgograd: Izd-vo VolGU, 2009. 490 p. (In Russ.)
15. Elbakyan L.S., Zaporotskova I.V. Polypropylene modified with carbon nanomaterials: structure, properties and application possibilities (a review). Polymers (basel). 2025;17(4):517. (In Russ.) https://doi.org/10.3390/polym17040517.
16. Elbakyan L.S., Zaporotskova I.V. Mechanism for creating a composite based on polypropylene modified with carbon nanotubes of different layer density. Izvestiya vysshikh uchebnykh zavedenii. Materialy elektronnoi tekhniki = Bulletin of higher educational institutions. Materials of electronic engineering. 2025;(1). (In Russ.) https://doi.org/10.17073/1609-3577j.met202501.646.
17. Yeletsky A.V. Sorption properties of carbon nanostructures. Uspekhi fizicheskikh nauk = Physics Uspekhi. 2004;174(11):1191-1231. (In Russ.)
Review
For citations:
Elbakyan L.S. Experimental studies of the mechanical characteristics of composite polymer materials based on polypropylene doped with carbon nanotubes. Proceedings of the Southwest State University. Series: Engineering and Technology. 2025;15(2):149-158. (In Russ.) https://doi.org/10.21869/2223-1528-2025-15-2-149-158