Physical and Chemical Properties of Secondary Powder Beryllium Bronze BrB2, Obtained by Electroerosion in Water
https://doi.org/10.21869/2223-1528-2022-12-3-8-22
Abstract
The purpose of this study was to study the physical properties (particle shape, size, specific surface area, granulometric composition), as well as the elemental composition of the powder obtained by electroerosion of conductive waste of beryllium bronze BrB2 in distilled water.
Methods. Beryllium bronze waste BrB2 was processed into powders at an experimental electroerosive dispersion plant in distilled water. The tasks set in the work were solved using modern equipment and complementary methods of physical materials science, including: grain composition and average particle size (laser particle size analyzer "Analysette 22 NanoTec"); shape and morphology of the particle surface (scanning electron microscope (SEM) "Quanta 200 FEG"); chemical composition (energy dispersive X-ray analyzer of the company "EDAX", built into the SEM "Quanta 600 3D".
Results. Based on the conducted experimental studies aimed at studying the physical properties and elemental composition of the powder obtained at the experimental installation by electroerosion of beryllium bronze waste BrB2 in an aqueous medium, the high efficiency of the use of electrodispersion technology, which provides, at low energy costs, the production of a new beryllium bronze powder suitable for industrial use, is shown. The following characteristics of powder materials obtained by electrodispersing beryllium bronze waste in distilled water have been experimentally established: the shape of the powder particles is spherical and elliptical, fine particles form agglomerates; particle sizes from 0.1 to 100 microns; the volumetric average diameter of the particles is 23 microns; the specific surface area is 0.19 m2/g, the main elements are Cu, Be, Ni, Fe, Si, and Al.
Conclusion. The conducted research on the production of a new electroerosive powder of beryllium bronze BrB2 and the study of its properties will allow for a consistent transition to advanced production technologies and materials through the use of promising, harmless to humans and the environment, low-tonnage and waste-free technology of electroerosive dispersion.
About the Authors
N. M. HoriakovaRussian Federation
Natalia М. Horiakova, Cand. of Sci. (Engineering), Associate Professor of the Department of Materials and Transport Technology
50 Let Oktyabrya str. 94, Kursk 305040
E. V. Ageeva
Russian Federation
Ekaterina V. Ageeva, Cand. of Sci. (Engineering), Associate Professor, Associate Professor of the Department of Materials Technology and Transport
50 Let Oktyabrya str. 94, Kursk 305040
K. V. Sadova
Russian Federation
Kristina V. Sadova, Student of the Department of Materials and Transport Technology
50 Let Oktyabrya str. 94, Kursk 305040
References
1. Lovshenko F. G., Lovshenko G. F., Lozikov I. A. Bronzy elektrotekhnicheskogo naznacheniya i osobennosti ikh izgotovleniya [Bronzes of electrotechnical purpose and features of their production]. Vestnik Belorussko-Rossiiskogo universiteta = Bulletin of the Belarusian-Russian University, 2012, No. 3 (36), pр. 36–52.
2. Tebyakin A. V., Focanov A. N., Podurazhnaya V. F. Mnogofunktsional'nye mednye splavy [Multifunctional copper alloys]. Trudy VIAM = Works of VIAM, 2016, vol. 12 (48), pp. 37–44.
3. Ageeva E. V., Ageev E. V., Horyakova N. M. Elektroerozionnye poroshki psevdosplava propiski, poluchennye v kerosine [Electroerosive powders of pseudo-alloy of residence permit obtained in kerosene]. Kursk, Universitetskaya kniga Publ., 2020. 178 p.
4. Ageeva E. V., Horyakova N. M., Sysoev A. A. Elektroerozionnye poroshki marki stali 12Kh17, poluchennye v kerosine [Electroerosive powders of steel grade 12X17, obtained in kerosene]. Kursk, Universitetskaya kniga Publ., 2020. 166 p.
5. Ageev E. V., Horyakova N. M. Psevdoproyavleniya vida na zhitel'stvo: poluchenie, primenenie, oformlenie [Pseudo-alloys of residence permit: obtaining, application, processing]. Kursk, Universitetskaya kniga Publ., 2020. 176 p.
6. Ageeva E. V., Ageev E. V., Horyakova N. M., Malukhov V. S. Poluchenie elektroerozionnykh nanoporoshkov medi iz otkhodov v srede kerosina [Production of Copper Electroerosion Nanopowders from Wastes in Kerosene Medium]. Zhurnal nano- i elektronnoi fiziki = Journal of nano- and electronic physics, 2014, vol. 6, no. 3, рр. 03011-1-03013-3.
7. Ageeva E. V., Horyakova N. M., Ageev E. V. Morfologiya mednogo poroshka, poluchennogo elektroiskrovym dispergirovaniem iz otkhodov [Morphology of Copper Powder Produced by Electrospark Dispersion from Waste]. Rossiiskie inzhenernye issledovaniya = Russian Engineering Research, 2014, vol. 34, no. 11, pp. 694–696.
8. Ageevа E. V., Ageev E. V., Horyakova N. M. Morfologiya i sostav prigodnogo dlya spekaniya elektroiskrovogo poroshka medi [Morphology and Composition of Copper Electrospark Powder Suitable for Sintering]. Rossiiskie inzhenernye issledovaniya = Russian Engineering Research, 2015, vol. 35, no. 1, pp. 33–35.
9. Ageev E. V., Avilova I. A., Horyakova N. M. Poluchenie elektroerozionnykh nanoporoshkov medi iz otkhodov vodnoi sredy i ego validatsiya fiziko-khimicheskimi metodami [Preparation of copper electroerosion nanopowders from waste of aquatic medium and its validation by physicochemical methods]. Prikladnaya mekhanika i materialy = Applied Mechanics and Materials, 2015, vol. 770, pp. 23–27.
10. Ageevа E. V., Latypov R. A., Horyakova N. M., Ageev E. V. Predstavlenie o fizikomekhanicheskikh i tribologicheskikh svoistvakh mednykh gal'vanicheskikh pokrytii, sformirovannykh s dobavleniem elektroerozionnogo mednogo nanoporoshka [Insight into physicomechanical and tribological properties of copper galvanic coatings formed with the addition of electroerosion copper nanopowder]. Rossiiskii zhurnal tsvetnykh metallov = Russian Journal of Non-Ferrous Metals, 2017, vol. 58, no. 2, pp. 161–167.
11. Ageev E. V., Ageevа E. V., Horyakova N. M. Issledovanie elementnogo sostava spechennogo poroshkovogo splava WNF-95, poluchennogo elektroerozionnym dispergirovaniem otkhodov v uglerodsoderzhashchei zhidkosti [Investigation of the elemental composition of the WNF-95 sintered powder alloy obtained by the electroerosive dispersion of waste in a carbon-containing liquid]. Seriya konferentsii IOP: Materialovedenie i tekhnika = IOP Conference Series: Materials Science and Engineering, 2020, vol. 1001, no. 012016.
12. Ageev E. V., Horakova N. M., Pikalov S. V., Korolev M. S., Podanov V. O. Study of the fractional composition of electroerosive powder materials of the tungsten nickel iron alloy obtained in lighting kerosene. International Conference on Modern Trends in Manufacturing Technologies and Equipment: Mechanical Engineering and Materials Science (ICMTMTE 2020), 2020, vol. 329, no. 02013.
13. Ageev E. V. Ustanovka dlya polucheniya nanodispersnykh poroshkov iz tokoprovodyashchikh materialov [Installation for the production of nanodisperse powders from conductive materials]. Patent RF, no. 2449859, 2012.
14. Ageevа E. V., Khorуakova N. M. Poluchenie elektroerozionnykh nanoporoshkov medi iz otkhodov v srede kerosina [Study of electrodeposited copper coatings obtained with the addition of electroerosion-copper nanoparticles]. Zhurnal nano- i elektronnoi fiziki = Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques, 2021, vol. 15, no. 5, pp. 999–1003.
15. Ageev E. V., Ageeva E. V., Horyakova N. M. Psevdosplavy propiski na osnove elektroerozionnykh materialov [Pseudo-alloys of residence permit based on electroerosive materials]. Kursk, Universitetskaya kniga Publ., 2021. 240 p.
16. Ageeva E. V., Loktionova O. G., Kutz V. V., Horyakova N. M. Issledovanie poristosti spechennykh obraztsov elektroerozionnoi poroshkovoi medi [Investigation of porosity of sintered samples of electroerosive powdered copper]. Izvestiya Yugo-Zapadnogo gosudarstvennogo universiteta = Proceedings Southwest State University, 2019, vol. 23, no. 2, pp. 65– 73.
17. Ageev E. V., Horyakova N. M., Sadova K. V. Morfologiya i elementnyi sostav poroshka psevdosplava VNZh-95, poluchennogo elektroerozionnym dispergirovaniem v kerosine [Morphology and elemental composition of psevdosplav VNJ-95 powder obtained by electroerosive dispersion in kerosen]. Izvestiya Volgogradskogo gosudarstvennogo tekhnicheskogo universiteta = Proceedings Volgograd State Technical University, 2020, no. 7 (242), рp. 15–20.
18. Ageev E. V., Horyakova N. M., Sadova K. V. Vybor optimal'nogo rezhima elektroerozionnogo dispergirovaniya otkhodov splava VNZh-95 v kerosine v zavisimosti ot proizvoditel'nosti protsessa EED [The choice of the optimal mode of electroerosive dispersion of the waste of the VNZh-95 alloy in kerosene according to the performance of the EED process]. Izvestiya Yugo-Zapadnogo gosudarstvennogo universiteta. Seriya: Tekhnika i tekhnologii = Proceedings Southwest State University. Series: Engineering and Technology, 2021, vol. 10, no. 2, pp. 8–19.
19. Ageev E. V., Horyakova N. M., Novikov E. P., Korolev M. S. Issledovanie poristosti splava VNZh, spechennogo iz elektroerozionnykh poroshkov, poluchennykh v vode [Investigation of the porosity of a residence permit alloy sintered from electroerosive powders obtained in water]. Izvestiya Volgogradskogo gosudarstvennogo tekhnicheskogo universiteta = Proceedings Volgograd State Technical University, 2021, no. 7 (254), pp. 32–35.
20. Ageev E. V., Ageeva E. V., Pikalov S. V., Horyakova N. M., Vorobyev E. A., Hardikov S. V., Novikov E. P. [Dimensional characteristics of electroerosive powders obtained from the waste of the alloy of residence permit in kerosene]. Upravlenie kachestvom na etapakh zhiznennogo tsikla tekhnicheskikh i tekhnologicheskikh system. Sbornik nauchnykh trudov 2-i Vserossiiskoi nauchno-tekhnicheskoi konferentsii [Quality management at the stages of the life cycle of technical and technological systems. Сollection of scientific tr. 2nd All-Russian Scientific and Technical Conf.]. Kursk, Southwest St. Univ. Publ., 2020, pp. 12– 15. (In Russ.)
Review
For citations:
Horiakova N.M., Ageeva E.V., Sadova K.V. Physical and Chemical Properties of Secondary Powder Beryllium Bronze BrB2, Obtained by Electroerosion in Water. Proceedings of the Southwest State University. Series: Engineering and Technology. 2022;12(3):8-22. (In Russ.) https://doi.org/10.21869/2223-1528-2022-12-3-8-22