The process of evaporation of a colloidal solution of stabilized Boron nitride nanoparticles
https://doi.org/10.21869/2223-1528-2024-14-3-65-75
Abstract
Purpose. Characterization of the chemical structure of boron nitride nanoparticles by IR spectroscopy during the evaporation of their colloidal system and their sizes by small-angle X-ray scattering.
Methods. The solvent evaporation process from the colloidal system was studied using a Nicolet iS 50 FT-IR spectrometer in the mid-IR range (400 – 4000 cm-1), with an attenuated total reflectance accessory with a diamond crystal (incident angle of 45°) and a liquid cell (200 μL). The sizes of the colloidal particles were determined using an smallangle X-ray scattering diffractometer in linear collimation mode (resolution 0.03 nm-1, copper anode X-ray tube 2.2 kW, λ = 0.154 nm, exposure time 30 s).
Results. The IR spectrum of boron nitride nanoparticles powder was measured, containing lines characteristic of cubic (952 cm-1) ) – c-BN and hexagonal crystalline phases (758, 1301, and 1372 cm-1) – h-BN. The average size of boron nitride nanoparticles in the colloidal system, according to small-angle X-ray scattering data, was 46 and 84 nm. The size of stearic acid, which acts as a stabilizing shell, was 0.8, 1.3, and 2.5 nm. Analysis of the IR spectra showed complete evaporation of the solvents (hexane and chloroform) from a drop of colloidal solution 1.2 mm thick within 30 minutes.
Conclusion. In this work, the average sizes of boron nitride nanoparticles stabilized with stearic acid in a colloidal system were determined and the process of its evaporation was studied.
Supporting agencies: This work was supported by the Ministry of Science and Higher Education of the Russian Federation (project No. 0851-2020-0035) and within the framework of the strategic academic leadership program "Priority-2030" (Agreement No. 075-15-2021-1213).
About the Authors
I. V. Loktionova
Southwest State University
Russian Federation
Russian Federation
Inna V. Loktionova, Candidate of Sciences (Physics and Mathematics), Senior Researcher of the Regional Center for Nanotechnology, Associate Professor of the Department of Nanotechnology, Microelectronics, General and Applied Physics
50 Let Oktyabrya Str. 94, Kursk 305040
P. V. Abakumov
Kursk State Medical University
Russian Federation
Russian Federation
Pavel V. Abakumov, Candidate of Sciences (Physics and Mathematics), Senior Teacher of the Physics, Informatics and Mathematics Department
K. Marx Str., Kursk 305041
A. P. Kuzmenko
Southwest State University
Russian Federation
Russian Federation
Alexander P. Kuzmenko, Doctor of Sciences (Physics and Mathematics), Professor, Chief Researcher of the Regional Center for Nano- technology
50 Let Oktyabrya Str. 94, Kursk 305040
A. I. Kolpakov
Southwest State University
Russian Federation
Russian Federation
Artem Ig. Kolpakov, Post-Graduate Student
50 Let Oktyabrya Str. 94, Kursk 305040
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Review
For citations:
Loktionova I.V., Abakumov P.V., Kuzmenko A.P., Kolpakov A.I. The process of evaporation of a colloidal solution of stabilized Boron nitride nanoparticles. Proceedings of the Southwest State University. Series: Engineering and Technology. 2024;14(3):65-75. (In Russ.) https://doi.org/10.21869/2223-1528-2024-14-3-65-75
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