techusguИзвестия Юго-Западного государственного университета. Серия: Техника и технологииProceedings of the Southwest State University. Series: Engineering and Technology2223-1528Юго-Западный государственный университет10.21869/2223-1528-2024-14-3-65-75techusgu-274Research ArticleФИЗИКАPHYSICSПроцесс испарения коллоидного раствора стабилизированных наночастиц нитрида бораThe process of evaporation of a colloidal solution of stabilized Boron nitride nanoparticleshttps://orcid.org/0009-0005-7272-2939ЛоктионоваИ. В.LoktionovaI. V.

Локтионова Инна Владимировна, кандидат физико-математических наук, старший научный сотрудник Регионального центра нанотехнологий, доцент кафедры нанотехнологий, микроэлектроники, общей и прикладной физики

ул. 50 лет Октября, д. 94, г. Курск 305040

Inna V. Loktionova, Candidate of Sciences (Physics and Mathematics), Senior Researcher of the Regional Center for Nanotechnology,  Associate Professor of the Department of Nanotechnology, Microelectronics, General and Applied Physics

50 Let Oktyabrya Str. 94, Kursk 305040

ms.chuhaeva@mail.ruhttps://orcid.org/0009-0009-1055-4019АбакумовП. В.AbakumovP. V.

Абакумов Павел Владимирович, кандидат физико-математических наук, старший  преподаватель кафедры физики, информатики и математики

ул. К. Маркса, д. 3, г. Курск 305041

Pavel V. Abakumov, Candidate of Sciences (Physics and Mathematics), Senior Teacher of the Physics, Informatics and Mathematics Department

K. Marx Str., Kursk 305041

bakumovpavel18@gmail.comhttps://orcid.org/0000-0001-7089-0692КузьменкоА. П.KuzmenkoA. P.

Кузьменко Александр Павлович, доктор физико-математических наук, профессор, главный научный сотрудник Регионального центра нанотехнологий

ул. 50 лет Октября, д. 94, г. Курск 305040

Alexander P. Kuzmenko, Doctor of Sciences (Physics and Mathematics), Professor, Chief  Researcher of the Regional Center for Nano- technology

50 Let Oktyabrya Str. 94, Kursk 305040

apk3527@mail.ruhttps://orcid.org/0009-0004-8571-8544КолпаковА. И.KolpakovA. I.

Колпаков Артем Игоревич, аспирант

ул. 50 лет Октября, д. 94, г. Курск 305040

Artem Ig. Kolpakov, Post-Graduate Student

50 Let Oktyabrya Str. 94, Kursk 305040

artem.kolpakov.96@mail.ruЮго-Западный государственный университетРоссияSouthwest State UniversityRussian FederationКурский государственный медицинский университетРоссияKursk State Medical UniversityRussian Federation2024240920241436575Copyright © Локтионова И.В., Абакумов П.В., Кузьменко А.П., Колпаков А.И., 20242024Локтионова И.В., Абакумов П.В., Кузьменко А.П., Колпаков А.И.Loktionova I.V., Abakumov P.V., Kuzmenko A.P., Kolpakov A.I.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://techusgu.elpub.ru/jour/article/view/274Цель

Цель. Характеризация химической структуры наночастиц нитрида бора по ИК-спектроскопии в процессе испарения их коллоидной системы и их размеров методом малоуглового рентгеновского рассеяния.

Методы

Методы. Процесс испарения растворителей из коллоидной системы изучался на ИК-Фурье-спектрометре Nicolet iS 50 в среднем ИК-диапазоне (400–4000 см-1) с приставкой нарушенного полного внутреннего отражения с алмазным кристаллом (угол падения 45о) и жидкостной ячейкой (200 мкл).

Размеры коллоидных частиц определялись на дифрактометре малоуглового рентгеновского рассеяния в режиме линейной коллимации (разрешение 0,03 нм–1, рентгеновская трубка с медным антикатодом 2,2 кВт, λ = 0,154 нм, время экспозиции 30 с).

Результаты

Результаты. Измерен ИК-спектр порошка наночастиц нитрида бора, который содержит линии, характерные для кубической (952 см-1) c-BN и гексагональных кристаллических (758, 1301 и 1372 см-1) h-BN фаз. Средние размеры наночастиц нитрида бора в коллоидной системе после ультразвуковой обработки составили по данным малоуглового рентгеновского рассеяния 46 и 84 нм при размерах стеариновой кислоты, выступающей в качестве стабилизирующей оболочки 0,8, 1,3 и 2,5 нм. Анализ ИК-спектров подтвердил полное испарение растворителей (гексана и хлороформа) из капли коллоидной системы толщиной 1,2 мм в течение 30 минут.

Заключение

Заключение. В работе определены средние размеры стабилизированных стеариновой кислотой наночастиц нитрида бора в коллоидной системе и изучен процесс ее испарения. 

Purpose

Purpose. Characterization of the chemical structure of boron nitride nanoparticles by IR spectroscopy during the evaporation of their colloidal system and their sizes by small-angle X-ray scattering.

Methods

Methods. The solvent evaporation process from the colloidal system was studied using a Nicolet iS 50 FT-IR spectrometer in the mid-IR range (400 – 4000 cm-1), with an attenuated total reflectance accessory with a diamond crystal (incident angle of 45°) and a liquid cell (200 μL). The sizes of the colloidal particles were determined using an smallangle X-ray scattering diffractometer in linear collimation mode (resolution 0.03 nm-1, copper anode X-ray tube 2.2 kW, λ = 0.154 nm, exposure time 30 s).

Results

Results. The IR spectrum of boron nitride nanoparticles powder was measured, containing lines characteristic of cubic (952 cm-1) ) – c-BN and hexagonal crystalline phases (758, 1301, and 1372 cm-1)  – h-BN. The average size of boron nitride nanoparticles in the colloidal system, according to small-angle X-ray scattering data, was 46 and 84 nm. The size of stearic acid, which acts as a stabilizing shell, was 0.8, 1.3, and 2.5 nm. Analysis of the IR spectra showed complete evaporation of the solvents (hexane and chloroform) from a drop of colloidal solution 1.2 mm thick within 30 minutes.

Conclusion

Conclusion. In this work, the average sizes of boron nitride nanoparticles stabilized with stearic acid in a colloidal system were determined and the process of its evaporation was studied.

нитрид борастеариновая кислотаиспарениеИК-спектроскопиямалоугловое рентгеновское рассеяние.boron nitridestearic acidevaporationIR spectroscopysmall-angle X-ray scatteringРабота выполнена при поддержке Министерства науки и высшего образования Российской Федерации (г/з № 0851-2020-0035) и в рамках реализации программы стратегического академического лидерства «Приоритет-2030» (Соглашение № 075-15-2021-1213).This work was supported by the Ministry of Science and Higher Education of the Russian Federation (project No. 0851-2020-0035) and within the framework of the strategic academic leadership program "Priority-2030" (Agreement No. 075-15-2021-1213).ReferencesNaclerio A. E., Kidambi P. R. A review of scalable hexagonal boron nitride (h‐BN) synthesis for present and future applications // Advanced Materials. 2023. Vol. 35, no. 6. P. 2207374. https://doi.org/10.1002/adma.202207374Naclerio A.E., Kidambi P.R. A review of scalable hexagonal boron nitride (h‐BN) synthesis for present and future applications. Advanced Materials. 2023;35(6):2207374. https://doi.org/10.1002/adma.202207374Hexagonal boron nitride for next‐generation photonics and electronics / S. Moon, J. Kim, J. Park, S. Im, J. Kim, I. Hwang [et al.] // Advanced Materials. 2023. Vol. 35, no. 4. P. 2204161. https://doi.org/10.1002/adma.202204161Moon S., Kim J., Park J., Im S., Kim J., Hwang I., et al. Hexagonal boron nitride for nextgeneration photonics and electronics. Advanced Materials. 2023;35(4):2204161. https://doi.org/10.1002/adma.202204161Advanced nano boron nitride architectures: Synthesis, properties and emerging applications / R. Y. Tay, H. Li, H. Wang, J. Lin, Z. K. Ng, R. Shivakumar [et al.] // Nano Today. 2023. Vol. 53. P. 102011. https://doi.org/10.1016/j.nantod.2023.102011Tay R.Y., Hongling Li, Hong Wang, Jinjun Lin, Zhi Kai Ng, Ranjana Shivakumar, et al. Advanced nano boron nitride architectures: Synthesis, properties and emerging applications. Nano Today. 2023;53:102011. https://doi.org/10.1016/j.nantod.2023.102011Improved thermal conductivity of polymer composites by noncovalent modification of boron nitride via tannic acid chemistry / L. Yu, S. Gao, D. Yang, Q. Wei, L. Zhang // Industrial & Engineering Chemistry Research. 2021. Vol. 60, no. 34. P. 12570–12578. https://doi.org/10.1021/acs.iecr.1c02217Yu L., Gao S., Yang D., Wei Q., Zhang L. Improved thermal conductivity of polymer composites by noncovalent modification of boron nitride via tannic acid chemistry. Industrial & Engineering Chemistry Research. 2021;60(34):12570–12578. https://doi.org/10.1021/acs.iecr.1c02217Challenges and solutions in surface engineering and assembly of boron nitride nanosheets / Z. Liu, A. D. Foroushani, D. Li, S. Mateti, J. Liu, F. Yan [et al.] // Materials Today. 2021. Vol. 44. P. 194–210. https://doi.org/10.1016/j.mattod.2020.11.020Liu Z., Foroushani A.D., Li D., Mateti S., Liu J., Yan F., et al. Challenges and solutions in surface engineering and assembly of boron nitride nanosheets. Materials Today. 2021;44:194–210. https://doi.org/10.1016/j.mattod.2020.11.020Glycine functionalized boron nitride nanosheets with improved dispersibility and enhanced interaction with matrix for thermal composites / X. Tian, N. Wu, B. Zhang, Y. Wang, Z. Geng, Y. Li // Chemical Engineering Journal. 2021. Vol. 408. P. 127360. https://doi.org/10.1016/j.cej.2020.127360Tian X., Wu N., Zhang B., Wang Y., Geng Z., Li Y. Glycine functionalized boron nitride nanosheets with improved dispersibility and enhanced interaction with matrix for thermal composites. Chemical Engineering Journal. 2021;408:127360. https://doi.org/10.1016/j.cej.2020.127360Highly-dispersed carboxymethyl cellulose and polyvinylpyrrolidone functionalized boron nitride for enhanced thermal conductivity and hydrophilicity / H. Li, W. Yang, N. Wu, L. Sun, P. Shen, X. Wang [et al.] // Applied Surface Science. 2023. Vol. 617. P. 156485. https://doi.org/10.1016/j.apsusc.2023.156485Li H., Yang W., Wu N., Sun L., Shen P., Wang X., et al. Highly-dispersed carboxymethyl cellulose and polyvinylpyrrolidone functionalized boron nitride for enhanced thermal conductivity and hydrophilicity. Applied Surface Science. 2023;617:156485. https://doi.org/10.1016/j.apsusc.2023.156485Functionalized boron–nitride nanotubes: First-principles calculations / C. Aguiar, M. Camps, N. Dattani, I. Camps // Applied Surface Science. 2023. Vol. 611. P. 155358. https://doi.org/10.1016/j.apsusc.2022.155358Aguiar C., Camps M., Dattani N., Camps I. Functionalized boron–nitride nanotubes: Firstprinciples calculations. Applied Surface Science. 2023;611:155358. https://doi.org/10.1016/j.apsusc.2022.155358Functionalized hexagonal boron nitride nanoplatelets for advanced cementitious nanocomposites / P. A. Danoglidis, C. M. Thomas, M. E. Maglogianni, M. C. Hersam, M. S. Konsta-Gdoutos // Cement and Concrete Composites. 2023. Vol. 141. P. 105127. https://doi.org/10.1016/j.cemconcomp.2023.105127Danoglidis P.A., Thomas C.M., Maglogianni M.E., Hersam M.C., Konsta-Gdoutos M.S. Functionalized hexagonal boron nitride nanoplatelets for advanced cementitious nanocomposites. Cement and Concrete Composites. 2023;141:105127. https://doi.org/10.1016/j.cemconcomp.2023.105127Boron nitride colloidal solutions, ultralight aerogels and freestanding membranes through one-step exfoliation and functionalization / W. Lei, V. N Mochalin, D. Liu, S. Qin, Y. Gogotsi, Y. I. Chen // Nature communications. 2015. Vol. 6, no. 1. P. 8849-1-6. https://doi.org/10.1038/ncomms9849.Lei W., Mochalin V.N., Liu D., Qin S., Gogotsi Y., Chen Y.I. Boron nitride colloidal solu-tions, ultralight aerogels and freestanding membranes through one-step exfoliation and functionalization. Nature communications. 2015;6(1):8849-6. https://doi.org/10.1038/ncomms9849Eco-friendly and scalable strategy to design electrically insulating boron nitride/polymer composites with high through-plane thermal conductivity / W. Jang, S. Lee, N. R. Kim, H. Koo, J. Yu, C.-M. Yang // Composites Part B: Engineering. 2023. Vol. 248. P. 110355. https://doi.org/10.1016/j.compositesb.2022.110355Eco-friendly and scalable strategy to design electrically insulating boron nitride/polymer composites with high through-plane thermal conductivity / W. Jang, S. Lee, N.R. Kim, H. Koo, J. Yu, C.-M. Yang. Composites Part B: Engineering. 2023;248:110355. https://doi.org/10.1016/j.compositesb.2022.110355Mazhar H., Adamson D. H., Al-Harthi M. A. Differently oxidized portions of functionalized hexagonal boron nitride // Materials Chemistry and Physics. 2023. Vol. 308. P. 128243. https://doi.org/10.1016/j.matchemphys.2023.128243Mazhar H., Adamson D.H., Al-Harthi M.A. Differently oxidized portions of functionalized hexagonal boron nitride. Materials Chemistry and Physics. 2023;308:128243. https://doi.org/10.1016/j.matchemphys.2023.128243Cubic and hexagonal boron nitride phases and phase boundaries / A. Biswas, G. A. Alvarez, M. Tripathi, J. Lee, T. S. Pieshkov, C. Li [et al.] // Journal of Materials Chemistry C. 2024. Vol. 12, no. 9. P. 3053–3062. https://doi.org/10.1039/D4TC00039KBiswas A., Alvarez G. A., Tripathi M., Lee J., Pieshkov T. S., Li C., et al. Cubic and hexagonal boron nitride phases and phase boundaries. Journal of Materials Chemistry C. 2024;12(9):3053–3062. https://doi.org/10.1039/D4TC00039KReview on various techniques for the development of thin film boron nitride coating on metal surfaces / M. Singh, H. Singh, Y. Sharma, M. Singh // AIP Conference Proceedings. 2024. Vol. 2986, no. 1. https://doi.org/10.1063/5.0192656Singh M., Singh H., Sharma Y., Singh M. Review on various techniques for the development of thin film boron nitride coating on metal surfaces. AIP Conference Proceedings. AIP Publishing, 2024;2986(1). https://doi.org/10.1063/5.0192656Оптические свойства и зонная структура ленгмюровских пленок нитрида бора / И. В. Локтионова, А. П. Кузьменко, А. И. Жакин, В. М. Емельянов, А. С. Сизов, А. П. Абакумов [и др.] // Известия Юго-Западного государственного университета. Серия: Техника и технологии. 2023. Т. 13, № 3. С. 105–116. https://doi.org/10.21869/2223-1528-2023-13-2-105-116Loktionova I.V., Kuzmenko A.P., Zhakin A.I., Emelyanov V.M., Sizov A.S., Abaku- mov A.P. Optical properties and band structure Lengmuir films of boron nitride. Izvestiya Yugo-Zapadnogo gosudarstvennogo universiteta. Seriya: Tekhnika i tekhnologii = Proceedings of the Southwest State University. Series: Engineering and Technologies. 2023;13(3):105–116. https://doi.org/10.21869/2223-1528-2023-13-2-105-116Lasalle B. S. I., Pandian M. S., Ramasamy P. Molecular interactions studies on chloroform in the environment of o-cresol: FTIR spectroscopy and quantum chemical calculations // Brazilian Journal of Physics. 2023 Vol. 53, no. 4. P. 97. https://doi.org/10.1007/s13538-023-01309-6Lasalle B.S.I., Pandian M.S., Ramasamy P. Molecular interactions studies on chloroform in the environment of o-cresol: FTIR spectroscopy and quantum chemical calculations. Brazilian Journal of Physics. 2023;53(4):97. https://doi.org/10.1007/s13538-023-01309-6Hydroisomerization of n-Hexane using acidified metal–organic framework and platinum nanoparticles / K. Sabyrov, J. Jiang, O. M. Yaghi, G. A. Somorjai // Journal of the American Chemical Society. 2017. Vol. 139, no. 36. P. 12382–12385. https://doi.org/10.1021/jacs.7b06629Sabyrov K., Jiang J., Yaghi O.M., Somorjai G.A. Hydroisomerization of n-Hexane using acidified metal–organic framework and platinum nanoparticles. Journal of the American Chemical Society. 2017;139(36):12382–12385. https://doi.org/10.1021/jacs.7b06629Reaction mechanism of stearic acid pyrolysis via reactive molecular dynamics simulation and TG-IR technology / Y. Zhang, C. Zhang, W. Li, Q. Xiao, F. Jiao, S. Xu [et al.] // Renewable Energy. 2023. Vol. 217. P. 119115. https://doi.org/10.1016/j.renene.2023.119115Zhang Y., Zhang C., Li W., Xiao Q., Jiao F., Xu S., et al. Reaction mechanism of stearic acid pyrolysis via reactive molecular dynamics simulation and TG-IR technology. Renewable Energy. 2023;217:119115. https://doi.org/10.1016/j.renene.2023.119115Effects of surface modification with stearic acid on the dispersion of some inorganic fillers in PE matrix / T. T. Nguyen, V. K. Nguyen, H. Pham, T. T. Pham, N. T. Duc // Journal of Composites Science. 2021. Vol. 5, no. 10. P. 270. https://doi.org/10.3390/jcs5100270Nguyen T.T., Nguyen V.K., Pham H., Pham T.T., Duc N.T. Effects of surface modification with stearic acid on the dispersion of some inorganic fillers in PE matrix. Journal of Composites Science. 2021;5(10):270. https://doi.org/10.3390/jcs5100270Effect of the stearic acid-modified TiO2 on PLA nanocomposites: Morphological and thermal properties at the microscopic scale / A. Deghiche, N. Haddaoui, A. Zerriouh, F. S. Eddine, D. Cavallo, A. Erto [et al.] // Journal of Environmental Chemical Engineering. 2021. Vol. 9, no. 6. P. 106541. https://doi.org/10.1016/j.jece.2021.106541Deghiche A., Haddaoui N., Zerriouh A., Eddine F.S., Cavallo D., Erto A., et al. Effect of the stearic acid-modified TiO2 on PLA nanocomposites: Morphological and thermal properties at the microscopic scale. Journal of Environmental Chemical Engineering. 2021;9(6):106541. https://doi.org/10.1016/j.jece.2021.106541

The authors declare that there are no conflicts of interest present.