techusguИзвестия Юго-Западного государственного университета. Серия: Техника и технологииProceedings of the Southwest State University. Series: Engineering and Technology2223-1528Юго-Западный государственный университет10.21869/2223-1528-2023-13-2-177-188techusgu-147Research ArticleФИЗИКАPHYSICSИнфракрасные сенсорные свойства многослойных нанокомпозитных пленок CuO/CNPs, полученных электрофоретическим синтезомIr Sensory Properties of Multilayer Nanocomposite CuO/CNPs Films Produced by Electroporetic SynthesisАунгН. В.AungN. W.

Ней Вин Аунг, аспирант кафедры нанотехнологий, микроэлектроники, общей и прикладной физики

50 лет Октября, д. 94, г. Курск 305040

Nay Win Aung, Post-Graduate Student of the Department of the of Nanotechnology, Micro- electronics and Engineering Physics

50 Let Oktyabrya Str. 94, Kursk 305040

https://orcid.org/0000-0002-5004-0823ПугачевскийМ. А.PugachevskiiМ. A.

Пугачевский Максим Александрович, доктор физико-математических наук, доцент, директор Регионального центра нанотехнологий

50 лет Октября, д. 94, г. Курск 305040

Maksim A. Pugachevskii, Dr. of Sci. (Physics and Mathematics), Associate Professor, Director of the Regional Center of Nanotechnology

50 Let Oktyabrya Str. 94, Kursk 305040

pmaximal@mail.ruhttps://orcid.org/0000-0003-4323-351XФилипповВ. В.FilippovV. V.

Филиппов Владимир Владимирович, доктор физико-математических наук, доцент, профессор кафедры математики и физики института естественных, математических и технических наук

ул. Ленина, д. 42, г. Липецк 398020

Vladimir V. Filippov, Dr. of Sci. (Physics and Mathematics), Associate Professor, Professor of the Department of Mathematics and Physics of the Institute of Natural, Mathematical and Technical Sciences

42 Lenina Str., Lipetsk 398020

ЕмельяновВ. М.YemelyanovV. M.

Емельянов Виктор Михайлович, доктор технических наук, профессор, главный научный сотрудник

50 лет Октября, д. 94, г. Курск 305040

Viktor M. Yemelyanov, Dr. of Sci. (Engineering), Professor, Chief Scientific

50 Let Oktyabrya Str. 94, Kursk 305040

Юго-Западный государственный университетРоссияSouthwest State UniversityRussian FederationЛипецкий государственный педагогический университет имени П. П. Семенова-Тян-ШанскогоРоссияLipetsk State Pedagogical University named after P. P. Semenov-Tyan-ShanskyRussian Federation202326072023132177188Copyright © Аунг Н.В., Пугачевский М.А., Филиппов В.В., Емельянов В.М., 20232023Аунг Н.В., Пугачевский М.А., Филиппов В.В., Емельянов В.М.Aung N.W., Pugachevskii М.A., Filippov V.V., Yemelyanov V.M.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://techusgu.elpub.ru/jour/article/view/147

Цель. Получение и исследование сенсорных свойств многослойных нанокомпозитных электрофоретических пленок CuO/CNPs в инфракрасном диапазоне.Методы. Исследование морфологии и размерного состава нанокомпозитных пленок CuO/CNPs с помощью атомно-силовой микроскопии и сканирующей электронной микроскопии; установление химического состава с помощью рентгеновской дифрактометрии, исследование сенсорной чувствительности при инфракрасном облучении оптоволоконным лазерным источником с длиной волны λ = 1064 нм; изучение временных характеристик наведенной фотоэлектродвижущей силы с помощью оптоэлектрических измерений (ADC L-CARD E2010D), сопряженных с персональным компьютером.Результаты. Методом электрофоретического синтеза на стеклянной подложке получены нанокомпозитные пленки CuO/CNPs толщиной от 0,1 до 1 мкм. Установлено, что нанокомпозитные пленки CuO/CNPs формируются за счет упорядоченного структурирования углеродных наночастиц вдоль направления электрического поля под действием электрофоретических сил. Одновременно за счет электролитического процесса на поверхности углеродных частиц образуется слой оксида меди с металлических электродов. Предельный размер углеродных частиц составил 50–70 нм в зависимости от параметров получения пленок. Разработана методика получения многослойных композитных пленок CuO/CNPs толщиной от одного до десяти слоев.Установлено, что при облучении синтезированных десятислойных нанопленок инфракрасным излучением интенсивностью 75 мВт/см-2 величина фотогенерированной ЭДС достигает 122,5 мВ.Заключение. Получены многослойные нанокомпозитные пленки CuO/CNPs с сенсорными свойствами в инфракрасном диапазоне. Установлено, что при увеличении толщины синтезированных пленок от одного до десяти слоев величина фото-ЭДС при ИК-облучении с интенсивностью 75 мВт/см-2 растет от 17 до 122,5 мВ.

Purpose. Formation and studying the sensory properties of multilayer nanocomposite electrophoretic CuO/CNPs films in the infrared range.Methods. Study of the morphology and size composition of CuO/CNPs nanocomposite films using atomic force microscopy and scanning electron microscopy; determination of the chemical composition using X-ray diffractometry, the study of sensory sensitivity under infrared irradiation with a fiber-optic laser source with a wavelength of λ = 1064 nm; study of the temporal characteristics of the induced photoelectromotive force using optoelectric measurements (ADC L-CARD E2010D) interfaced with a personal computer.Results. Nanocomposite CuO/CNPs films 0.1 to 1 µm thick were obtained by electrophoretic synthesis on a glass substrate. It has been established that CuO/CNPs nanocomposite films are formed due to the ordered structuring of carbon nanoparticles along the direction of the electric field under the action of electrophoretic forces. At the same time, due to the electrolytic process, a layer of copper oxide from metal electrodes is formed on the surface of the carbon particles. The limiting size of carbon particles was 50-70 nm, depending on the parameters of film production. A technique has been developed for producing multilayer CuO/CNPs composite films with a thickness of one to ten layers. It has been established that when the synthesized ten-layer nanofilms are irradiated with infrared radiation with an intensity of 75 mW/cm-2, the value of the photogenerated EMF reaches 122.5 mV.Conclusion. Multilayer nanocomposite CuO/CNPs films with infrared sensor properties were obtained. It has been established that with an increase in the thickness of the synthesized films from one to ten layers, the photo-EMF under IR irradiation with an intensity of 75 mW/cm-2 increases from 17 to 122.5 mV.

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The authors declare that there are no conflicts of interest present.